2.Basic Properties and Description
of ERF and MRF
ERF and MRF are characterized by a huge increase of their apparent viscosity
under the influence of a electrical or accordingly a magnetic field.
Without the influence of a field they are in general real thin liquids
whereas they behave as real solids, provided the field dependent yield
stress is not exceeded, when the field becomes switched on.
They usually consist of a base fluid and solid particles. The volume fraction
of the particles is between 20% and 60%. The build up of more or less branched
particle chains is responsible for the increase of apparent viscosity.
These particles are attracted to each other by electrical or accordingly
magnetic forces. Shearing of the fluid first leads to a stretching and
under higher stresses to a break up of the particle chains. Steady recombination
of chain parts provides for increased viscosity even under high shear rates.
ERF and MRF belong to the group of Non Newtonian Fluids and their description
as Bingham-Plastics is generally recognized. Hence, the following relation
between shear stress and shear rate is appropriate:
with:
- shear
stress [Pa]
- field
induced shear stress [Pa]
- dynamic
viscosity [Pa s] (some times called
)
- shear
rate [
]
As counterpart to the constant dynamic viscosityof
Newtonian Fluids an apparent viscosity
is
defined for Bingham Plastics. It can be influenced by the electrical or
magnetic field strength.
The dynamic viscosity is
mostly determined by the base fluid. It is mainly temperature dependent.
The field induced shear stress depends
on the electrical or magnetic field strength. For this dependence some
theoretical models have been derived but neither one is yet able to reflect
these relations properly. As a rule of thumb one can assume that
increases
quadratic with increasing electrical or magnetic field strength.
In the case of the shear stress being below,
the fluid behaves as a solid and hence the shear stress is proportional
to the shear strain (not to the shear rate). The proportionality factor
is called shear modul G. When exceeding the yield stress the fluid becomes
liquid. This liquid state is characterized by a linear increase of shear
stress with shear rate. The proportionality factor is, as can be seen from
the Bingham model, the static viscosity
.
It is generally accepted that the transition from solid to liquid (increase
of shear stress) occurs at a different shear stress than the transition
from liquid to solid (reduction of shear stress). Both transitional shear
stresses are in the same order of magnitude. The yield stress of the change
from solid to liquid is called ' static yield stress' whereas
the reverse characteristic yield stress is called 'dynamic yield stress'
.
The question which one is higher has to be answered different from fluid
to fluid. The case
however
is the most likely to be encountered and it is to explained easier with
the breakup behaviour of particle chains. Sorely for the most fluids are
no measured values for
and
existant
yet. Hence, one can obtain only one yield stress
from
the shear stress - shear rate-curves.
ERF are suspensions of electrically polarizable particles in a base fluid.
This leads to a movement of particles to the poles under the impact of
a direct voltage. Hence, it builds up a enriched zone next to the poles
and a rarefied zone in the middle between them. This means that the particle
concentration deviates everywhere from the optimum concentration, leading
to a huge decrease of available yield stress. This process is called 'electrophoresis'.
It can be prevented when using alternating fields.In this case one should
also account for the influence of the field frequency on the yield stressand
choose the optimum frequency, which is in the order of magnitude of several
hundert Hertz. An analog effect for MRF was not encountered yet.
When using ERF or MRF special attention has to be drawn to the temperature
dependence of their properties. Good fluids are already nowadays characterized
by a good constancy of their properties. The dependence between yield stress
and temperature is different from fluid to fluid. The biggest temperature
problem for ERF results from the huge increase of current density
with increasing temperature. Basic viscosity sligthly decreases with temperature
for ERF as well as for MRF. For relative permeability of
MRF one can expect a very small decrease with increasing temperature.
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